HIGH SOLID ANAEROBIC DIGESTION OF MUNICIPAL SOLID WASTE

Anaerobic digestion (AD) is viewed as an attractive method for waste stabilization prior to landfills as pre-treatment to reduce significant pollution load to the environment Optimizing anaerobic digestion process aims to maximize organic waste conversion to biogas at short digestion period, The optimization of high solid concentration of MSW in a laboratory scale reactor was carried out to know the maximum biogas production yield, This paper presents the findings of the study on high solid AD process in single which involves enhanced pre-stage (hydrolysis and acidification) and methane phase,


I INTRODUCTION
Unmanaged pollutants from organic farm waste, industrial and municipal solid waste (MSW) degrades the environment and methane emitted from their decomposition contributes to global climate change [ 1 ], Under modem environmental regulations in general and MSW (Management and Handling) Rules, 2000 promulgated by MOEF, Govt. of India in particular, these wastes are becoming difficult to disposed off using traditional means.
There are various technologies for MSW at Global level, However, in India, open dumping is commonly practiced, The huge quantity of MSW generated is mostly disposed off on land without adapting any precautionary measures. This results in contamination of air and water media as well as influences the health of the society [2,3], Though landfill sites are the sources of methane, the landfill gas needs to be purified to increase the methane concentration, Moreover, methane can be recovered for a limited period of time depending upon the life of the landfill site, the quantity of waste dumped at a particular site, and the methane potential of the dumped waste [4], Thus, the sanitation problem contributed by MSW is alarming and needs immediate attention on priority basis, Lands are becoming scarce for disposal of waste, which pressurizes to look for integrated approach for MSW management. Also, due to an increasing awareness of economic and environmental cost of conventional landfilling, recent interest is to develop the technologies that accelerate the degradation of the organic fraction of MSW, One option is to digest the organic fraction prior to landfilling, or preserve landfill space by accelerating the decomposition of the organic fraction within the landfill. Composting, one of the processing options, is being used in many of the municipalities in India. Inferior quality of compost and high cost has resulted in low market demand. Hence biomethanation of MSW has drawn special attention of the researchers, stakeholders and policy makers. The Government of India has announced a national policy to promote and provide financial support to waste based power projects [5 ]. AD has been up to now essentially applied to wastewater management (6,7]. However, anaerobic processing of organic solid waste fits in well with the new requirements for waste management. In connection with the utilization of renewable energies and the rising relevancy of climate protection, it can be affinned that AD for the treatment of MSW has a high potential for future development. AD for wastewater is being practiced since long back when AD was mainly aimed as a treatment alternative. For MSW, it is processing option and it is better to considered as biomethanation. The biomethanation process can be carried out both in a single step as well as two steps. In a single step process, the biomethanation is carried out in a single reactor. The present investigation is aimed to study the performance of innovative single stage high solid digestion (SSHS).  Tables 1 and 2. Laboratory-scale unit ( called as a set from now onwards) consists of glass aspirator bottle of suitable capacity (such as 2 L or 5 L) as reactor, another glass aspirator bottle of suitable size (such as 1.5 L or 3 L) for biogas filled with acidified brine solution along with a conical flask of suitable capacity to collect displaced brine solution. Suitable arrangement for pH electrode was provided with each set The schematic of a series of single phase experimental set-up is shown in Figure 1.

MSW was obtained from
Initially, batch studies were carried out in aspirator bottles of different capacity to select essential factors influencing the SSHS approach development with emphasis on total solid concentration, C/N ratio, and temperature.

Methods for chemical characterization of MSW samples
The chemical analysis of MSW samples was carried out as per Standard Methods. BIS No. 9234/1979,

Effect of total solid concentrations
In different glass containers, total solid concentrations from 20-50% were prepared. Desired total concentrations were prepared considering initial moisture content in MSW and accordingly additional water was mixed or sun-dried samples were taken. Here, no pretreatment or pre-seeding was done and experiments were carried out at prevailing room temperature.
The experiments were conducted in five sets of bottle of 2 L capacities. In the first set, 450 g sun-dried MSW was mixed with 1600 mL of tap water (having a total solid concentration of approximately 20%) and it was ensured that the container was in air tight condition. In the second, third, fourth sets, 590 g, 820 g and 700 g MSW was mixed with 1376 mL, 1230 mL and 700 mL of tap water with a total solid concentration of 30, 40 and 50% and kept in separate 2 L glass bottles ensuring air tight condition. The biogas yield was observed by displacement of acidified saturated brine solution. The experiments were conducted at room temperature (29-31 °C).
Each container was provided with a pH electrode to enable to observe pH variation inside the mixture in the containers. Gas onset and total quantity of gas from each set was monitored and the yield of biogas was calculated for one kg of VS.

Effect of pre-seeding
To study the effect of pre-seeding the MSW, experiment was performed with solid concentration of 20%. For this, in the one set, 450 g sun-dried MSW was mixed with 1600 mL of tap water with a total solid concentration of approximately 20% and was filled and ensured that the container is in air tight condition. In the another set, 450 g sun-dried MSW was mixed with 1200 mL of tap water along with 400 mL of liquid culture from the operating digester (corresponding to 5% seed) thoroughly mixed with the sample. In this set also, the total solid concentration was around 20%. Each container was provided with a pH electrode to enable to observe pH variation inside the mixture in the containers Gas onset and total quantity of gas from each set was monitored and the yield of biogas was calculated for one kg of VS.

Confirmation of optimum total solid concentrations
After selecting the suitable optimum total solid concentrations, the experiments were being further repeated using 5 litre glass reactors, which were also provided with pH electrodes. The studies were conducted using 40, 50 and 60% total solids concentration. In these experiments, 1200 g, 1500 g and 1800 g of MSW are mixed with 1800 mL, 1500 mL and 1200 mL of tap water to make total solid concentrations of approximately 40, 50 and 60% respectively in a 5 L bottle ensuring airtight condition under controlled conditions with a temperature of 29-31 °C. The biogas yield was observed by displacement of acidified saturates brine solution.

Effects of C/N ratio
The experimental set for 50% total solid concentration, which gives maximum biogas yield during the experiment period, was selected for further study with varying C/N ratio. The experiments were conducted by selecting appropriate C/N ratios (between 20-60) in 2 L reagent bottles.
This run pertains to the effect of different C/N ratios. In the first set, for the adjustment ofC/N ratio of 20, 5 00 g of MSW was mixed with 28. 3 0 g KNO 3 dissolved in 5 00 ml tap water. For preparing C/N ratio of 3 0, 5 00 g of MSW was mixed with I 0. 9 g of KNO 3 dissolved in 500 ml of tap water. In the third set, 5 00 g of MSW was mixed with 5 00 ml of tap water maintaining the C/N ratio of 43 . 5 . In the fourth set, 5 00 g of MSW was mixed with I 23 .5 g of cardboard and 5 00 ml of tap water adjusting the C/N ratio of 5 0. In the last set, 3 7 7 g of MSW was mixed with 123 . 5 g of cardboard and 2. 18 g of KNO 3 dissolved in 500 ml water with the adjustment of C/N ratio of 60. The biogas yield was observed by displacement of acidified saturated brine solution. The experiments were carried out under controlled conditions at a temperature of 29-3 1 °C. Another set was also repeated at various C/N ratios under ambient room temperature.

Effects of temperature
To study the effect of temperature, one run of experiments were carried out at various C/N ratios under controlled conditions at a temperature of 29-3 1 °C. Another run was also repeated at same C/N ratios under ambient room temperature.

RES UL TS AND DISCUSSION
The pH data in a single phase shows that initially pH of the mixture is in between 6. 5 to 7 but after 15 -20 days, the pH value get decreases because of the production of VFAs by indigenious microorganisms present in the MSW which converts the soluble carbonaceous matter. During 20-25 days, pH values are between 4.0 to 5.5 because of the accumulation of VFA mostly acetic acid. After 25 -3 2 days, the pH value increases because of the degradation of the VFA into biogas by the methanogenic bacteria developed in the container. During 3 2-35 days again, the pH value get decreases which may be due to the production of VF A, which is not sufficient to activate the methanogenic microbes present in the system and hence it does not yield biogas anymore.
The pH data also indicates that higher the total solid concentration, lower the pH (less than 5.5) because it contains higher soluble carbonaceous matter ultimately gives high volume of biogas. But, lower total solid concentration (20% and 3 0%) gives higher pH (> 5 . 5 ) because of containment of less amount of soluble carbonaceous matter and hence the biogas yield is less.
The experiments reveal that the biogas production starts at around IO days after tilling the waste in the container. The biogas quality generated in containers with 20% and 5 0% of total solid concentration is more compared to 3 0% and 40% total solid concentration. The results indicate that without culture addition, methanogenic activity takes place, Figure 2 indicates that the biogas quantity is more for 20 and 50 % solid than for 20% with culture, It was confirmed that MSW without preparation is suitable for biomethanation, SSHD is feasible, which may prove beneficial for developing for commercial application, MSW with total solid concentration of 50% gives better perfomrnnce at 29-31 °C, Similarly, MSW with 20% total solid concentration gives more biogas yield than 30-40% total solid, which is less compared to 50% total solid concentration, The addition of seed (culture) is not necessary, The pH trends are initially near 7,0 which later decreases to 5,6,Thus, pre-processing of MSW and addition of culture are not obligatory,