Heavy metal removal from stormwater runoff by sorption

Författare

  • Hulya Genr-Fuhrman Technical University of Denmark, Denmark
  • Peter S. Mikkelsen Technical University of Denmark, Denmark
  • Anna Ledin Technical University of Denmark, Denmark

DOI:

https://doi.org/10.15626/Eco-Tech.2005.022

Nyckelord:

Heavy metal; Sorption; Filtration; Stormwater runoff; Multiple sorbents

Abstract

In this study, several sorbents (i.e. alumina, activated bauxsol coated sand (ABCS), bark,
bauxsol coated sand (BCS), fly ash (FA), granulated activated carbon (GAC), iron oxide
coated sand (IOCS), natural zeolite (NZ), sand, and spine!) are investigated with the longterm goal of developing a feasible technology for heavy metal removal during secondary
treatment of storm water. The sorbents are tested in batch tests for their As, Cd, Cr, Cu, Ni and
Zn removal efficiency from synthetic stormwater samples, where all of these metals coexisted at a starting pH of 6.5. It is found that each sorbent has different affinity to the heavy
metals, with heavy metal cations (i.e. Cd, Cu, Ni and Zn) removed more effectively than
heavy metal anions (i.e. As and Cr) by all sorbents except IOCS, which has a high affinity
towards As. The results further indicated that alumina and BCS outperform the other sorbents,
possibly due to high surface area of alumina and the favourable sorption sites of BCS;
whereas NZ, sand and bark were the least efficient. On the other hand, although FA
effectively retained Cd, Ni and Zn, the leaching of As, Cr, and Cu is a concern.

Statistik

Laddar statistik...

Referenser

Vivona , M.A., Mooney, G., 1997. Remediation of contaminated stormwater canal at Miami International Airport. Wat. Eng Manag., 144, 24-29.

Jang, A., Seo, Y,, Bishop , PL, 2005, The removal of heavy metals in ur ban runoff by sorption on mulch, Environ. Poll.o, 133, 117-127. https://doi.org/10.1016/j.envpol.2004.05.020

Dillon, P., Pavelic, P., Massmann, G., Barry, K,, Correll, R., 2001 . Enhancement of the membrane filtration index (MF !) for determining the clogging potentiaol of turbid urban stormwater and reclaimed water used for aquifer storage and recover y, Desalination, 140, 153-165.

Makepea ce , DX., Smith, D,W,, Stanley , S.J., 1995 . Urban stormwater quality:summary of contaminant data . Crit. Rew. Env. Sci. Techn.o, 25, 93-139. https://doi.org/10.1080/10643389509388476

Marzal, P., Seco, A., Gabaldon , C., 1996. Cadmium and zinc adsorption onto activated carbon :influence of temperature, pH and metal/car bon ration , J. Chem. Tech. Biolech.o, 66, 279-285, https://doi.org/10.1002/(SICI)1097-4660(199607)66:3<279::AID-JCTB506>3.0.CO;2-K

Gens;-Fuhrrnan, H., Bregnhoj, H,, McConchie, D., 2005. Arsenate removal from water using sand-red mud columns, Wat. Res. , 39, 2944-2954. https://doi.org/10.1016/j.watres.2005.04.050

Matheickal, J,T,, Yu, Q,, 1 997, Biosorption of lead(II) from aqueous solutions by phellinus badius, Min. Engo, 10 , 947- 957.

Vasconcelos, L.A .T., Bes;a, C,G.G., 1997. Chemical activation of fine bark to improve its adsorption capacity of heavy metal ions. Part ! :by acid treatment. Eur. Wat. Poll. Cont.o, 7, 41-46 .

Kosmulski, M,, 1996. Adsorption of cadmium on alumina and silica : analysis of the values of stability constants of surface complexes calcula ted for different parameters of triple layer model. Coll. Surf A., 117, 201-214.

Wang , J,, Teng, X., Wang, H., Ban, H., 2004. Characterising the metals adsorption capabilities of a class F coal fly ash. Env. Sci. Tech.o, 38, 6710-6715. https://doi.org/10.1021/es049544h

Urbonas, R., 1999. Design of a sand filter for stormwater quality enhancement. Wat. Res.o, 71 , 102-113. https://www.jstor.org/stable/25045180

Benjamin, M,M., Sletten, R.S ., Bailey , R.P., Bennett, T. 1996 . Sorption and filtration of metals using iron-oxide coated sand . Wat. Res. 30 , 2609-2620. https://doi.org/10.1016/S0043-1354(96)00161-3

Apak, R., Giii;li.i, K., Turgut, M.H., 1998 . Modelling of Copper(II), Cadmium(II), and Lead(II) adsorption on red mud . J. Coll. Interj Sci. 2 30, 122o-1 30. https://doi.org/10.1006/jcis.1998.5457

Stumm, W., 1992. Chemistry of solid-water interface . John Wiley & Sons, Inc ., Canada, p 20.

Danish Environmental Protection Agency ( DEPA) (1996). Danish discharge standards BEK nr 921 af 0 8/10/1996 .

Taty-Costodes, V.C., Fauduet, H., Porte, C., 2003. Removal of Cd(II) and Pb ions, from aqueous solutions by adsorption onto sawdust of Pin.us slvestris.o, J. Haz. Mat.o, B10 5, 121-142. https://doi.org/10.1016/j.jhazmat.2003.07.009

A I-Asheh, S., Banal, F., Al-Omari, R., Duvnjak, Z., 2000. Predictions of binary sorption isotherms for the sorption of heavy metals by pine bark using single isotherm data . Chemosphere 41 , 659-665. https://doi.org/10.1016/S0045-6535(99)00497-X

Bailey , S .E., Olin, T.J., Bricka, R.M., Adrian , D.D., 1999. A review of potentially lowcost sorbents for heavy metals. Wat. Res, 33, 2469-2479. https://doi.org/10.1016/S0043-1354(98)00475-8

Parwate, A .V., Bhole, A .G. 2003. Studies on removal of Cr(Vl) and Ni(II) using lowcost adsor bents. J. Ins. Engo, 83, 45- 50.

Chen, J.P., Wang , X., 2000. Removing copper, zinc, and lead ion by granular activated carbon in pretreated fixed- bed columns. Sep. Purif. Techn. 19, 157-157 https://doi.org/10.1016/S1383-5866(99)00069-6

Lo, S., Jeng , H., Lai, C., 1997. Characteristics and adsorption properties of iron oxide coated sand . Wat, Sci. Tech.., 35, 63-70. https://doi.org/10.1016/S0273-1223(97)00115-7

Lai, C.H., Lo, S .L ., Chiang, H.L ., 2000. Adsorption/desorption properties of copper ions on the surface of iron/coated sand using BET and EDAX analyses. Chemosphere, 41 , 1249-1255. https://doi.org/10.1016/S0045-6535(99)00534-2

Has an y, S.M., Chaudhary, M.H., 1996. Sorption potential of Haro river sand for the removal of antimony from acidic aqueous solution. Appl. Rad. Jsotop., 47, 467-471. https://doi.org/10.1016/0969-8043(95)00310-X

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Publicerad

2019-10-17