Reusing of sodium silicate as a raw material in glass industry: byproduct of sodium borohydride production

Authors

  • Aysel Kanturk Yildiz Technical University, Department of Chemical Engineering, Turkey
  • Muge Sari Yildiz Technical University, Department of Chemical Engineering, Turkey
  • Özgul Dere Yildiz Technical University, Department of Chemical Engineering, Turkey
  • Sabriye Piskin Yildiz Technical University, Department of Chemical Engineering, Turkey

DOI:

https://doi.org/10.15626/Eco-Tech.2007.011

Keywords:

Sodium silicate; Reusing; Vitrification; Sodium borohydride; clean energy.

Abstract

Global energy and ecology problems continue to grow because of burning of fossil fuels,
environmental pollution, decrease of energy sources and difficulties in storing electricity.
Hydrogen has great potential to solve these problems as an environmentally clean energy
carrier and as a way to reduce reliance on imported energy sources. Hydrogen can be stored
and transported safely in the form of sodium borohydride (NaBH4) due to its high theoretical
hydrogen yield by weight (10.6%) in applications where H2 gas is used, e.g., proton exchange
membrane (PEM) fuel cells. NaBH4 is synthesized from boron minerals (borax, ulexite,
colemanite ... ) by the thermal-chemical reactions.
The main aim of this paper is the investigation of reusing of Na2SiO3, obtained from Na8H4
production based on the conversion reaction of borosilicate glass, as a raw material in glass
industry. The by-product, was defined as Na2SiO3 (PDF number: 00-016 -0818) by XRD (XRay Diffractometer) technique, was then vitrificated into a glass for utilization. The obtained
glass was characterized by scanning electron microscopy with energy dispersive spectroscopy
(SEM/EDS) analysis and FT-IR (Fourier Transformer-Infrared spectroscopy) techniques. The
results show that by-product Na2SiO3 can be reused as a raw material in glass industry.

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References

Schlinger, H, L, Brown, H, C, Finholt, A, E,, Gilbert, J, R,, Hoekstra, H, R, ve Hyde, E,K,, 1953, Sodium borohydrite, its hydrolysis and its use as a reducing agent and in the generation of hydrogen, Journal of American Chemical Society, 75, 215-219. https://doi.org/10.1021/ja01097a057

Kim, J,, Lee, H,, Han, S,, Kim, H,, Song, M,, Lee, J,, 2004, Production of hydrogen from sodium borohydride in alkaline solution: development of catalyst with high performance, International Journal of Hydrogen Energy, 29, 263-267. https://doi.org/10.1016/S0360-3199(03)00128-9

http://en.wikipedia.org

Kojima, Y,, Haga, T,, 2003, Recycling process of sodium metaborate to sodium. borohydride, International Journal of Hydrogen Energy, 28, 989-993. https://doi.org/10.1016/S0360-3199(02)00173-8

Li, Z, P,, Morgazaki, N., Liu, B. H., Suda S., 2003. Preparation of sodium borohydride by the reaction of MgH2 with dehydrate borax through ball milling at room temperature, Journal of Alloys Compounds, 349, 232-236. https://doi.org/10.1016/S0925-8388(02)00872-1

Kantiirk, A., Piskin, S, Innovation in sodium borohydride production process from borosilicate glass with sodium under hydrogen atmosphere: high hydrogen process, International Journal of Hydrogen Energy. In Press https://doi.org/10.1016/j.ijhydene.2007.04.047

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Published

2007-12-12